US 11,851,537 B2
Methods for making a plasticized polymer, methods for making a composition using the plasticized polymer, and compositions comprising the plasticized polymer
Steven D. Gray, Mequon, WI (US); Kimberly E. Secrist, Wauwatosa, WI (US); and Miao Hu, Pewaukee, WI (US)
Assigned to Bostik, Inc., Wauwatosa, WI (US)
Filed by BOSTIK, INC., Wauwatosa, WI (US)
Filed on Sep. 27, 2019, as Appl. No. 16/584,981.
Claims priority of provisional application 62/737,954, filed on Sep. 28, 2018.
Prior Publication US 2020/0102428 A1, Apr. 2, 2020
Int. Cl. C08J 3/22 (2006.01); C09D 7/65 (2018.01); C08L 91/00 (2006.01); C09D 191/00 (2006.01); C09J 11/08 (2006.01); C09J 191/00 (2006.01); C09K 3/10 (2006.01); C10M 101/00 (2006.01); C10M 107/04 (2006.01); C10M 177/00 (2006.01)
CPC C08J 3/226 (2013.01) [C08L 91/00 (2013.01); C09D 7/65 (2018.01); C09D 191/00 (2013.01); C09J 11/08 (2013.01); C09J 191/00 (2013.01); C09K 3/10 (2013.01); C10M 101/00 (2013.01); C10M 107/04 (2013.01); C10M 177/00 (2013.01); C08L 2310/00 (2013.01); C09K 2200/062 (2013.01); C10M 2203/003 (2013.01); C10M 2205/0225 (2013.01)] 25 Claims
 
1. A method for making a plasticized polymer comprising the step of:
polymerizing a polymerizable monomer in a reaction medium comprising a plasticizer and in the presence of a catalyst system for a time and temperature sufficient to form a plasticizer system comprising the plasticized polymer, wherein the plasticizer system further comprises at least 25 wt % of the plasticizer and is suitable for use as a component in an adhesive, wherein:
the plasticizer is selected from the group consisting of mineral oil, liquid polybutene, hydrocarbon oil, synthetic oil, a dibenzoate, a phosphate, a phthalate ester, and an ester of a monoglycol or a polyglycol, and the reaction medium contains less than 10 wt % solvent.