	US 12,492,287 B2
	Organic frame material having zinc containing iso-molybdic acid metal, method of manufacturing the same, and application thereof
Mingyang He, Changzhou (CN); Qun Chen, Changzhou (CN); Junfeng Qian, Changzhou (CN); Shengchun Chen, Changzhou (CN); Lu Tian, Changzhou (CN); and Meijun Wei, Changzhou (CN)
Assigned to Changzhou University, Changzhou (CN)
Filed by Changzhou University, Changzhou (CN)
Filed on Jul. 27, 2022, as Appl. No. 17/875,378.
Claims priority of application No. 202111412756.3 (CN), filed on Nov. 25, 2021.
Prior Publication US 2023/0159699 A1, May 25, 2023
Int. Cl. C08G 63/08 (2006.01); C07F 11/00 (2006.01); C08G 63/82 (2006.01); C08G 63/83 (2006.01)

CPC C08G 63/823 (2013.01) [C07F 11/005 (2013.01); C08G 63/08 (2013.01); C08G 63/83 (2013.01)]

9 Claims

1. An organic frame material having a zinc containing isopoly-molybdic acid metal comprising:

a three-dimensional network structure having zinc ions coordinated with 2,3,5,6-tetrafluoro-bis (1,2,4-triazole-1-methyl) benzene ligands and trinuclear molybdate anions, the chemical formula of the three-dimensional network structure being [Zn (tfbtb) (Mo₃O₁₀) (H₂O)],

wherein tfbtb is 2,3,5,6-tetrafluoro-bis (1,2,4-triazole-1-methyl) benzene ligand, and Mo₃O₁₀is a trinuclear molybdate anion.