| CPC H01L 21/02164 (2013.01) [C23C 16/0272 (2013.01); C23C 16/401 (2013.01); C23C 16/45527 (2013.01); H01L 21/02211 (2013.01); H01L 21/0228 (2013.01)] | 23 Claims |

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1. A method of selectively depositing silicon and oxygen-comprising material on a first surface of a substrate relative to a second surface of the substrate by a cyclic deposition process, the method comprising
providing a substrate in a reaction chamber;
providing a metal catalyst or metalloid catalyst into the reaction chamber in a vapor phase, wherein the catalyst is a compound comprising B, Zn, Mg, Al, Sn, or Ga;
providing a silicon precursor comprising an alkoxy silane compound into the reaction chamber in a vapor phase; and
providing an oxygen precursor comprising oxygen and hydrogen into the reaction chamber in vapor phase to form silicon and oxygen-comprising material on the first surface.
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