| CPC C21D 9/46 (2013.01) [C21D 6/001 (2013.01); C21D 6/002 (2013.01); C21D 6/004 (2013.01); C21D 6/005 (2013.01); C21D 6/007 (2013.01); C21D 6/008 (2013.01); C21D 8/0205 (2013.01); C21D 8/0226 (2013.01); C21D 8/0236 (2013.01); C21D 8/0263 (2013.01); C22C 38/001 (2013.01); C22C 38/002 (2013.01); C22C 38/005 (2013.01); C22C 38/008 (2013.01); C22C 38/02 (2013.01); C22C 38/04 (2013.01); C22C 38/06 (2013.01); C22C 38/10 (2013.01); C22C 38/105 (2013.01); C22C 38/12 (2013.01); C22C 38/14 (2013.01); C22C 38/22 (2013.01); C22C 38/26 (2013.01); C22C 38/28 (2013.01); C22C 38/30 (2013.01); C22C 38/34 (2013.01); C22C 38/38 (2013.01); C22C 38/42 (2013.01); C22C 38/48 (2013.01); C22C 38/50 (2013.01); C22C 38/60 (2013.01); C25D 3/44 (2013.01); C25D 5/36 (2013.01); C21D 2211/008 (2013.01)] | 7 Claims |
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1. A steel sheet comprising, as a chemical composition, in a unit of mass %:
C: 0.20% or more and 0.45% or less;
Si: 0.01% or more and 2.50% or less;
Mn: 1.20% or more and 3.50% or less;
P: 0.040% or less;
S: 0.010% or less;
Al: 0.001% or more and 0.100% or less;
N: 0.0001% or more and 0.0100% or less;
Ti: 0.005% or more and 0.100% or less;
B: 0% or more and 0.010% or less;
O: 0.006% or less;
Mo: 0% or more and 0.50% or less;
Nb: 0% or more and 0.20% or less;
Cr: 0% or more and 0.50% or less;
V: 0% or more and 0.50% or less;
Cu: 0% or more and 1.00% or less;
W: 0% or more and 0.100% or less;
Ta: 0% or more and 0.10% or less;
Ni: 0% or more and 1.00% or less;
Sn: 0% or more and 0.050% or less;
Co: 0% or more and 0.50% or less;
Sb: 0% or more and 0.050% or less;
As: 0% or more and 0.050% or less;
Mg: 0% or more and 0.050% or less;
Ca: 0% or more and 0.040% or less;
Y: 0% or more and 0.050% or less;
Zr: 0% or more and 0.050% or less;
La: 0% or more and 0.050% or less;
Ce: 0% or more and 0.050% or less; and
a remainder consisting of Fe and impurities,
wherein a Ti content and a N content satisfy the following formula 1,
at a sheet thickness ¼ position, a metallographic structure includes 90% or more of martensite in terms of volume fraction,
at the sheet thickness ¼ position, a number density of TiC having a circle equivalent diameter of 1 to 500 nm is 3.5×104 particles/mm2 or more,
at the sheet thickness ¼ position, a value of a median value of a Mn concentration+3σ is 5.00% or less,
a hardness measured at the sheet thickness ¼ position is 1.30 times or more a hardness measured at a position 50 μm deep from a surface of the steel sheet, and
a tensile strength is 1310 MPa or more,
Ti−3.5×N≥0.003 (formula 1)
here, element symbols Ti and N in the formula 1 mean the Ti content and the N content of the steel sheet.
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