CPC H01M 4/525 (2013.01) [C01G 53/50 (2013.01); H01M 4/505 (2013.01); H01M 10/0525 (2013.01); C01P 2002/50 (2013.01); C01P 2002/85 (2013.01); C01P 2004/03 (2013.01); C01P 2004/32 (2013.01); C01P 2004/84 (2013.01); C01P 2006/40 (2013.01); H01M 2004/028 (2013.01)] | 15 Claims |
1. A novel precursor particle for preparing a cathode active material comprising:
a transition metal precursor particle containing one or more transition metals; and
one or more of an alkali metal and an alkaline earth metal,
wherein the alkali metal and the alkaline earth metal are contained in one or more of inner and outer parts of the transition metal precursor particle,
wherein the novel precursor particle has a composition represented by the following Formula 1:
[(1-x-Y)A2CO3*xAOH*yA2O]/[(1-a-b)M(OH)2*aMOOH*bM(OH1-c)2] (1)
wherein
0≤x≤1, 0≤y≤1, 0≤a≤1, 0≤b≤1, 0≤c≤1;
A is at least one alkali metal and/or alkaline earth metal; and
M comprises one or more transition metals stable in a tetracoordinate or hexacoordinate structure, and
wherein the molar ratio (A/M) of total alkali metal and/or alkaline earth metal (A) to total transition metal (M) is more than 0 and is not more than 1.5.
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