1. A plasma etching apparatus, comprising: a chamber; a gas supply unit configured to supply processing gas to the chamber; a plasma generator configured to generate plasma in the chamber; and a controller configured to cause: providing a substrate having a metal-containing mask provided with a preset opening pattern on an etching target film including silicon oxide film in the chamber; forming a fluoro-carbon protective film on the metal-containing mask provided with the preset opening pattern, using a first processing gas including a first fluoro-carbon gas and oxygen containing gas; and etching the silicon oxide film by plasma using a second processing gas including a second fluoro-carbon gas having a larger F ratio with respect to C than the first fluoro-carbon gas.
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