US 12,152,147 B2
Thermally conductive silicone gel composition
Takumi Kataishi, Aichi (JP); Yuko Kimura, Aichi (JP); Mai Sugie, Aichi (JP); Makoto Iwai, Aichi (JP); and Setsuo Kikuchi, Aichi (JP)
Assigned to Fuji Polymer Industries Co., Ltd., Aichi (JP)
Appl. No. 17/425,888
Filed by Fuji Polymer Industries Co., Ltd., Nagoya (JP)
PCT Filed Aug. 6, 2020, PCT No. PCT/JP2020/030172
§ 371(c)(1), (2) Date Jul. 26, 2021,
PCT Pub. No. WO2021/140694, PCT Pub. Date Jul. 15, 2021.
Claims priority of application No. 2020-000447 (JP), filed on Jan. 6, 2020.
Prior Publication US 2022/0169857 A1, Jun. 2, 2022
Int. Cl. C08L 83/04 (2006.01); C08K 3/013 (2018.01); C08L 83/06 (2006.01); H01L 23/373 (2006.01); C08G 77/12 (2006.01); C08G 77/20 (2006.01); C08K 3/22 (2006.01); C08K 3/28 (2006.01)
CPC C08L 83/04 (2013.01) [C08K 3/013 (2018.01); C08L 83/06 (2013.01); C08G 77/12 (2013.01); C08G 77/20 (2013.01); C08K 2003/2227 (2013.01); C08K 2003/2296 (2013.01); C08K 2003/282 (2013.01); C08L 2203/20 (2013.01); C08L 2314/08 (2013.01); H01L 23/3737 (2013.01)] 11 Claims
 
1. A thermally conductive silicone gel composition comprising the following components A to F:
A. a linear organopolysiloxane having two alkenyl groups per molecule;
B. a linear organohydrogenpolysiloxane having two Si—H groups per molecule, the Si—H groups being present at both ends of a molecular chain;
C. an organohydrogenpolysiloxane having three or more Si—H groups per molecule;
D. a linear organohydrogenpolysiloxane having one Si—H group per molecule;
E. a platinum catalyst in an amount required for curing; and
F. a thermally conductive filler, a volume occupied by the thermally conductive filler being 1 to 6 times a volume occupied by the components A to E,
wherein the components A to F are cured,
wherein the thermally conductive silicone gel composition comprises 1 to 300 parts by weight of the component B, 0.1 to 20 parts by weight of the component C, and 0.1 to 50 parts by weight of the component D with respect to 100 parts by weight of the component A, wherein a ratio of the Si—H group to the alkenyl group (Si—H group/alkenyl group) in all the components A to D is 0.5 to 2.0, and
wherein an oil bleeding rate of the thermally conductive silicone gel composition is 0.45 wt % or less, which is calculated according to the following Formula I and measured in such a manner that the thermally conductive silicone gel composition is formed into a molded product with a width of 25 mm, a length of 25 mm, and a thickness of 3.0 mm, and then the molded product is sandwiched between polytetrafluoroethylene (PTFE) filter papers, compressed to a thickness of 1.8 mm, and allowed to stand for 24 hours in an atmosphere of 80° C.,
Oil bleeding rate (wt %)=[(weight of the PTFE filter papers after test−weight of the PFTE filter papers before test)/weight of the thermally conductive silicone gel composition before the test]×100  [Formula I].