| CPC C12P 17/02 (2013.01) [C12N 9/0077 (2013.01); C12N 9/14 (2013.01); C12P 5/007 (2013.01); C12P 19/18 (2013.01); C12P 19/56 (2013.01); C12Y 303/0201 (2013.01); C12Y 504/99008 (2013.01)] | 20 Claims |
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1. A method for making mogrol or mogroside, comprising:
providing a recombinant microbial host cell expressing a heterologous enzyme pathway catalyzing the conversion of isopentenyl pyrophosphate (IPP) and dimethylallyl pyrophosphate (DMAPP) to mogrol or mogroside, the heterologous enzyme pathway comprising:
a farnesyl diphosphate synthase (FPPS),
a squalene synthase (SQS),
a squalene epoxidase (SQE) catalyzing the formation of 2,3;22,23-dioxidosqualene from squalene,
a triterpene cyclase (TTC) catalyzing the formation of 24,25-epoxycucurbitadienol from 2,3;22,23-dioxidosqualene,
an epoxide hydrolase (EPH) catalyzing the formation of 24,25-dihydroxycucurbitadienol from 24,25-epoxycucurbitadienol, and
a cytochrome P450 enzyme catalyzing the formation of mogrol from 24,25-dihydroxycucurbitadienol;
wherein the cytochrome P450 enzyme comprises an amino acid sequence having at least 85% sequence identity with SEQ ID NO: 171; and
culturing the host cell under conditions for producing the mogrol or mogroside.
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