US 12,148,926 B2
Positive electrolyte active material for secondary battery, preparation method thereof, and lithium secondary battery including same
Sang Min Park, Daejeon (KR); Ji Hye Kim, Daejeon (KR); Tae Gu Yoo, Daejeon (KR); Wang Mo Jung, Daejeon (KR); and Gi Beom Han, Daejeon (KR)
Assigned to LG Energy Solution, Ltd., Seoul (KR)
Appl. No. 17/279,759
Filed by LG Chem, Ltd., Seoul (KR)
PCT Filed Oct. 21, 2019, PCT No. PCT/KR2019/013805
§ 371(c)(1), (2) Date Mar. 25, 2021,
PCT Pub. No. WO2020/085731, PCT Pub. Date Apr. 30, 2020.
Claims priority of application No. 10-2018-0129161 (KR), filed on Oct. 26, 2018.
Prior Publication US 2022/0037658 A1, Feb. 3, 2022
Int. Cl. H01M 4/525 (2010.01); C01G 53/00 (2006.01); H01M 4/02 (2006.01); H01M 4/04 (2006.01); H01M 4/505 (2010.01); H01M 10/0525 (2010.01)
CPC H01M 4/525 (2013.01) [C01G 53/50 (2013.01); H01M 4/0471 (2013.01); H01M 4/505 (2013.01); H01M 10/0525 (2013.01); H01M 2004/021 (2013.01); H01M 2004/028 (2013.01)] 14 Claims
 
1. A positive electrode active material for a secondary battery, the material being a lithium composite transition metal oxide including nickel (Ni), cobalt (Co), and manganese (Mn),
wherein the lithium composite transition metal oxide is represented by Formula 1 below,
LipNi1-(x1+y1+z1+w1)Cox1Mny1Maz1Mbw1O2+δ  [Formula 1]
wherein
Ma includes at least two elements of Zr, Al, V, Co, or Mg as first dopants,
Mb includes at least two elements of Ti, Y, Sr, Nb, Ba, or Ca as second dopants, and
1≤p≤1.5,0<x1≤0.5,0<y1≤0.5,0<z1≤0.025,0<w1≤0.015, and −0.1≤8≤1, and
and
the lithium composite transition metal oxide is in a form of particles having a crystallite size of 170 nm to 300 nm, and wherein:
the first dopants are contained in the total content of 2,000 ppm to 6,000 ppm; and
the second dopants are contained in the total content of more than 1,500 ppm to 3,000 ppm.