| CPC H01L 21/28568 (2013.01) [C23C 16/06 (2013.01); C23C 16/45525 (2013.01); H01L 23/53257 (2013.01); H10B 12/34 (2023.02); H10B 41/27 (2023.02); H10B 43/27 (2023.02)] | 28 Claims |

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1. A method comprising:
depositing a molybdenum (Mo)-containing layer in a feature on a substrate; and
depositing tungsten (W) on the Mo-containing layer to thereby fill the feature with tungsten, wherein the average crystallite size of the tungsten is at least 20 nm.
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