| CPC C23C 16/04 (2013.01) [C23C 16/0281 (2013.01); C23C 16/20 (2013.01); C23C 16/45534 (2013.01); C23C 16/56 (2013.01); C23C 28/341 (2013.01)] | 21 Claims |

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1. A method of selectively depositing different materials on a first surface and a second different surface of a substrate, the method comprising one or more first deposition cycles comprising:
exposing the first and the second surfaces of the substrate to a passivation agent such that a passivation layer is selectively formed on the first surface relative to the second surface;
exposing the first surface, having the formed passivation layer, and the second surfaces of the substrate to a first reactant such that a first element from the first reactant is selectively deposited on the second surface relative to the first surface; and
exposing the first surface, having the passivation layer, and the second surface, having the deposited first element, s of the substrate to a second reactant, wherein, such that a first material selectively forms on the first surface simultaneously with a second material selectively forming on the second surface, is selectively formed on the first surface and a second different material is selectively formed on the second surface simultaneously in the one or more first deposition cycles, and wherein one or more of an etch rate, a density, a conductivity, and a refractive index of the first material differs from that of the second material by at least about 5%.
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