| CPC C22C 45/04 (2013.01) [C04B 35/56 (2013.01); C04B 35/5805 (2013.01); C04B 35/62222 (2013.01); C04B 35/65 (2013.01); C22C 32/0047 (2013.01); C23C 4/08 (2013.01); C23C 4/12 (2013.01); C23C 4/18 (2013.01); C04B 2235/3804 (2013.01); C04B 2235/3817 (2013.01); C04B 2235/405 (2013.01); C04B 2235/9669 (2013.01); C23C 4/129 (2016.01)] | 19 Claims |

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1. A method comprising obtaining a substrate, forming a coating of an amorphous metal alloy, heating the coating, and transforming at least a portion of the amorphous metal alloy into a composite comprising an amorphous metal ceramic composite, wherein the amorphous metal ceramic composite comprises the amorphous metal alloy and a ceramic formed from the amorphous metal alloy, wherein the amorphous metal alloy starts to crystallize at a temperature above 600° C.; and further comprising forming a second layer of the coating of the amorphous metal alloy and bonding with a previous layer of the coating on the substrate.
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