US 12,473,497 B2
Processes and systems for removing coke particles from a pyrolysis effluent
Thomas T. Hirst, Houston, TX (US); George Stephens, Huffman, TX (US); and David Spicer, Houston, TX (US)
Assigned to ExxonMobil Engineering and Technology Company, Spring, TX (US)
Appl. No. 18/267,476
Filed by EXXONMOBIL CHEMICAL PATENTS INC., Baytown, TX (US)
PCT Filed Dec. 30, 2021, PCT No. PCT/US2021/065604
§ 371(c)(1), (2) Date Jun. 15, 2023,
PCT Pub. No. WO2022/150218, PCT Pub. Date Jul. 14, 2022.
Claims priority of provisional application 63/135,259, filed on Jan. 8, 2021.
Claims priority of application No. 21161155 (EP), filed on Mar. 8, 2021.
Prior Publication US 2024/0059980 A1, Feb. 22, 2024
Int. Cl. C10G 9/16 (2006.01); B01D 45/06 (2006.01)
CPC C10G 9/16 (2013.01) [B01D 45/06 (2013.01); C10G 2300/107 (2013.01); C10G 2300/1074 (2013.01); C10G 2300/1081 (2013.01)] 25 Claims
OG exemplary drawing
 
1. A hydrocarbon pyrolysis process, comprising:
introducing a hydrocarbon feed into a pyrolysis furnace comprising a first radiant coil and a second radiant coil;
pyrolysing at least a portion of a first quantity of the hydrocarbon feed in the first radiant coil to produce a first hydrocarbon effluent and to deposit coke on an inner surface of the first radiant coil;
pyrolysing at least a portion of a second quantity of the hydrocarbon feed in the second radiant coil to produce a second hydrocarbon effluent and to deposit coke on an inner surface of the second radiant coil;
decreasing a flow rate of the hydrocarbon feed into the first radiant coil while maintaining a flow rate of the hydrocarbon feed into the second radiant coil;
introducing a decoking feed comprising steam or a mixture of steam and air into the first radiant coil of the pyrolysis furnace to remove at least a portion of the coke deposited on the inner surface of the first radiant coil and to produce a de-coking effluent comprising steam and a plurality of coke particles;
indirectly exchanging heat from the second hydrocarbon effluent to water, steam, or a mixture thereof to produce a cooled second hydrocarbon effluent;
indirectly exchanging heat from the de-coking effluent to water, steam, or a mixture thereof to produce a cooled de-coking effluent;
mixing the cooled second hydrocarbon effluent and the cooled de-coking effluent to produce a combined effluent;
introducing the combined effluent into an inlet conduit of a separator under conditions that provide ≥80 wt. % of the plurality of coke particles with a Stokes number of ≥10;
removing ≥55 wt. % of the plurality of coke particles in the combined effluent from a first exit conduit of the separator, and
removing a coke-lean hydrocarbon effluent comprising ≤45 wt. % of the plurality of coke particles in the combined effluent from a second exit conduit of the separator, wherein the first exit conduit is coupled to the inlet conduit, and wherein the second exit conduit is coupled to the inlet conduit, wherein:
the plurality of coke particles is introduced into a coke catch apparatus,
a flow control device couples the first exit conduit to the coke catch apparatus, and
a total length of the first exit conduit and the flow control device is ≤8 times an inner diameter of the first exit conduit.