| CPC B32B 5/18 (2013.01) [B32B 17/066 (2013.01); C01B 33/1546 (2013.01); C01B 33/155 (2013.01); C01B 33/1585 (2013.01); B32B 2250/40 (2013.01); B32B 2266/057 (2016.11); B32B 2266/126 (2016.11); B32B 2307/304 (2013.01); B32B 2307/414 (2013.01); B32B 2419/00 (2013.01); C01P 2006/32 (2013.01); C01P 2006/60 (2013.01)] | 33 Claims |

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1. An article comprising a glass substrate and a silica aerogel sheet, the silica aerogel sheet being adhered to the glass substrate and being formed from a precursor material comprising methyl silicate 51 and having a thickness in a range of from 1.5 to 15 mm, a haze of less than 2.5%, a visible transmission of greater than 98%, a thermal conductivity of less than 20 mW/m*K, and a global structural similarity index measure of greater than 0.80, wherein the silica aerogel sheet is self-supporting such that the silica aerogel sheet retains sheet form without being adhered to a substrate.
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