US 12,472,458 B2
Air separation processes using zeolite ITQ-55
Yu Wang, Lebanon, NJ (US); Edward W. Corcoran, Jr., Nazareth, PA (US); Pavel Kortunov, Flemington, NJ (US); and Avelino Corma Canos, Valencia (ES)
Assigned to EXXONMOBIL TECHNOLOGY AND ENGINEERING COMPANY, Spring, TX (US)
Filed by ExxonMobil Technology and Engineering Company, Annandale, NJ (US)
Filed on Jul. 26, 2022, as Appl. No. 17/814,931.
Claims priority of provisional application 63/265,230, filed on Dec. 10, 2021.
Prior Publication US 2023/0182066 A1, Jun. 15, 2023
Int. Cl. B01D 53/047 (2006.01); B01D 53/04 (2006.01); B01D 53/26 (2006.01)
CPC B01D 53/0473 (2013.01) [B01D 53/0423 (2013.01); B01D 2253/108 (2013.01); B01D 2253/304 (2013.01); B01D 2253/342 (2013.01); B01D 2257/104 (2013.01); B01D 2257/80 (2013.01); B01D 2259/402 (2013.01)] 14 Claims
OG exemplary drawing
 
1. A process of adsorbing oxygen from a feed stream comprising oxygen, nitrogen, and water, comprising passing the feed stream through one or more beds of adsorbent comprising a first adsorbent selective for water so as to adsorb water from the feed stream and a second adsorbent selective for oxygen so as to adsorb oxygen from the feed stream, thereby producing a rejection product stream enriched in nitrogen and depleted in oxygen and water, wherein the first adsorbent comprises a dehydration adsorbent and the second adsorbent comprise ITQ-55; wherein the zeolite ITQ-55 has a mean crystal particle size within the range of from about 0.1 microns to about 40 microns; wherein the feed stream is exposed to the first adsorbent at effective conditions to remove water from the feed stream; and wherein the feed stream is exposed to the second adsorbent at effective conditions for performing a kinetic separation, in which the kinetic separation exhibits greater kinetic selectivity for oxygen than for nitrogen.