US 12,140,906 B2
External additive for toner and toner
Ichiro Kanno, Chiba (JP); Kaoru Yoshida, Ibaraki (JP); and Hayato Ida, Ibaraki (JP)
Assigned to CANON KABUSHIKI KAISHA, Tokyo (JP)
Filed by CANON KABUSHIKI KAISHA, Tokyo (JP)
Filed on Jan. 19, 2022, as Appl. No. 17/648,333.
Claims priority of application No. 2021-009603 (JP), filed on Jan. 25, 2021; and application No. 2021-196672 (JP), filed on Dec. 3, 2021.
Prior Publication US 2022/0236655 A1, Jul. 28, 2022
Int. Cl. G03G 9/097 (2006.01); C08G 77/04 (2006.01)
CPC G03G 9/09775 (2013.01) [C08G 77/04 (2013.01)] 10 Claims
 
1. An external additive for toner comprising a particle of a silicon polymer having a siloxane bond and a Si—R1 bond, wherein
the R1 represents an alkyl group having from 1 to 6 carbon atoms,
in a chart obtained by 29Si—NMR measurement of the external additive, where a total peak area attributed to the external additive is denoted by A, and a peak area attributed to the Si—R1 bond is denoted by B, the A and the B satisfy a following formula (1), and
in the chart obtained by 29Si—NMR measurement of the external additive, where a total peak area attributed to the silicon polymer is denoted by SA, and a peak area attributed to a T unit structure is denoted by S3, the SA and the S3 satisfy a following formula (2);

OG Complex Work Unit Math