US 12,471,346 B2
Memory array isolation structures
Kuo-Chang Chiang, Hsinchu (TW); Hung-Chang Sun, Kaohsiung (TW); Sheng-Chih Lai, Hsinchu (TW); TsuChing Yang, Taipei (TW); and Yu-Wei Jiang, Hsinchu (TW)
Assigned to Taiwan Semiconductor Manufacturing Co., Ltd., Hsinchu (TW)
Filed by Taiwan Semiconductor Manufacturing Co., Ltd., Hsinchu (TW)
Filed on Apr. 14, 2023, as Appl. No. 18/301,113.
Application 18/301,113 is a division of application No. 17/119,346, filed on Dec. 11, 2020, granted, now 11,640,974.
Claims priority of provisional application 63/045,992, filed on Jun. 30, 2020.
Prior Publication US 2023/0253464 A1, Aug. 10, 2023
Int. Cl. H10D 64/68 (2025.01); G11C 11/22 (2006.01); H10D 30/67 (2025.01); H10D 30/69 (2025.01); H10D 64/01 (2025.01)
CPC H10D 64/033 (2025.01) [G11C 11/223 (2013.01); G11C 11/2255 (2013.01); G11C 11/2257 (2013.01); H10D 30/6755 (2025.01); H10D 30/701 (2025.01); H10D 64/689 (2025.01)] 20 Claims
OG exemplary drawing
 
1. A method, comprising:
patterning a first trench extending through a first conductive line;
depositing a memory film along sidewalls and a bottom surface of the first trench;
depositing an oxide semiconductor (OS) layer over the memory film, the OS layer extending along the sidewalls and the bottom surface of the first trench;
depositing a first dielectric material over and contacting the OS layer, wherein depositing the first dielectric material comprises simultaneously supplying a first hydrogen-comprising precursor at a first flow rate and a second hydrogen-free precursor at a second flow rate, wherein a ratio of the second flow rate of the second hydrogen-free precursor to the first flow rate of the first hydrogen-comprising precursor is at least 60, and wherein after depositing the first dielectric material, a hydrogen concentration at an interface between the first dielectric material and the OS layer is 3 at % or less;
depositing a second dielectric material over the first dielectric material to fill a remaining portion of the first trench;
etching a second trench through the first dielectric material and the second dielectric material, wherein the first trench extends through the OS layer; and
filling the second trench with a first conductive material to form a bit line, wherein the bit line extends through the OS layer and overlaps the OS layer.