US 12,134,712 B2
Two component (2K) curable composition
Nishant Tale, Pune (IN); Krunal Trivedi, Vapi (IN); and Jayesh P. Shah, Pune (IN)
Assigned to Henkel AG & Co. KGaA, Duesseldorf (DE)
Filed by Henkel AG & Co. KGaA, Duesseldorf (DE)
Filed on May 18, 2022, as Appl. No. 17/747,770.
Application 17/747,770 is a continuation of application No. PCT/EP2020/081093, filed on Nov. 5, 2020.
Claims priority of application No. 201941046830 (IN), filed on Nov. 18, 2019.
Prior Publication US 2022/0332990 A1, Oct. 20, 2022
Int. Cl. B32B 41/00 (2006.01); C08K 3/10 (2018.01); C08K 3/36 (2006.01); C09J 7/10 (2018.01); C09J 133/14 (2006.01); C09J 167/06 (2006.01)
CPC C09J 133/14 (2013.01) [C08K 3/10 (2013.01); C08K 3/36 (2013.01); C09J 7/10 (2018.01); C09J 167/06 (2013.01); C09J 2301/408 (2020.08)] 17 Claims
 
1. A two-component (2K) curable composition comprising:
(A) a first component comprising:
i) at least one cyanoacrylate monomer represented by Formula 1:
H2C═C(CN)—COOR  (1)
wherein: R is selected from C1-C18 alkyl, C3-C18 cycloalkyl, C2-C15 alkenyl, C6-C18 aryl, C7-C15 aralkyl and C3-C15 allyl; and,
ii) peroxide catalyst; and,
iii) at least one cure accelerator for said at least one cyanoacrylate monomer of (A)i);
(B) a second component comprising:
i) at least one free radically curable compound; and,
ii) at least one transition metal compound,
wherein, when said first and second components are mixed together, the peroxide catalyst initiates cure of said free radically curable compound and the transition metal compound(s) initiates cure of the cyanoacrylate monomer, and
wherein said at least one free radically curable compound comprises at least one unsaturated polyester polymer containing at least two cycloolefinic double bonds (UPS).