| CPC H01M 4/8663 (2013.01) [H01M 4/8828 (2013.01); H01M 8/1004 (2013.01); H01M 2004/8684 (2013.01)] | 15 Claims |

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1. An anode catalyst layer with high reversal tolerant capability, comprising:
an anode inner catalyst layer between a proton exchange membrane and a gas diffusion layer; and
an anode outer catalyst layer between the gas diffusion layer and the anode inner catalyst layer,
wherein at least the anode inner catalyst layer contains a reversal tolerant catalyst and a hydrophilic additive, and a content of the hydrophilic additive in the anode inner catalyst layer is not less than a content of the hydrophilic additive in the anode outer catalyst layer, or a water retention capability of the anode inner catalyst layer is not less than a water retention capability of the anode outer catalyst layer, and
wherein the hydrophilic additive includes at least one of a molecular sieve, a nanoporous superabsorbent gel or a superporous hydrogel microparticle, and a surfactant containing a hydrophilic group;
wherein only the anode inner catalyst layer contains the hydrophilic additive.
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