| CPC C09D 5/185 (2013.01) [B33Y 40/00 (2014.12); C09D 5/002 (2013.01); C09D 7/61 (2018.01); C09D 7/63 (2018.01); C09D 105/00 (2013.01); C09D 129/04 (2013.01); C09D 133/20 (2013.01); C09D 161/06 (2013.01); C09D 197/005 (2013.01); B33Y 10/00 (2014.12)] | 20 Claims |

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1. A multimodal coating, the multimodal coating comprising:
a medium;
a structural framework embedded in the medium forming an intumescent coating, the intumescent coating configured to undergo intumescent expansion of an outermost coating of the medium upon heating; and
a metastable material, the metastable material including calcium oxalate, and wherein the metastable material is configured to absorb heat through endothermic reactions as the metastable material undergoes phase transitions.
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