US 12,460,023 B2
Catalyst pretreatment and feeding system for polypropylene production
Reza Khankal, Humble, TX (US); Joel A. Mutchler, Porter, TX (US); Bryan M. Garner, Alvin, TX (US); and James E. Hein, Houston, TX (US)
Assigned to Chevron Phillips Chemical Company LP, The Woodlands, TX (US)
Filed by Chevron Phillips Chemical Company LP, The Woodlands, TX (US)
Filed on Jan. 18, 2022, as Appl. No. 17/577,502.
Application 17/577,502 is a continuation of application No. 17/071,527, filed on Oct. 15, 2020, granted, now 11,254,761.
Prior Publication US 2022/0135710 A1, May 5, 2022
This patent is subject to a terminal disclaimer.
Int. Cl. C08F 10/06 (2006.01); C08F 110/06 (2006.01)
CPC C08F 10/06 (2013.01) 20 Claims
OG exemplary drawing
 
1. A process for pre-polymerizing propylene, comprising:
adding a catalyst and propylene to a first mixer;
mixing the catalyst and propylene in the first mixer to form a first catalyst suspension comprising the catalyst and propylene;
flowing the first catalyst suspension from the first mixer to a second mixer, wherein the second mixer is a stirred tank;
adding a co-catalyst and an electron donor agent to the first catalyst suspension;
pre-polymerizing propylene in the second mixer to form a second catalyst suspension comprising propylene, catalyst particles coated with polypropylene, the co-catalyst, and the electron donor agent;
feeding the second catalyst suspension to a polymerization reactor; and
introducing additional co-catalyst and electron donor agent to the polymerization reactor,
wherein the co-catalyst is added to the first catalyst suspension at a location in a transfer line that is upstream of the location where the electron donor agent is added.