| CPC B01D 61/50 (2013.01) [B01D 63/085 (2013.01); B01D 2313/14 (2013.01); B01D 2325/42 (2013.01)] | 16 Claims |

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1. A spacer for positioning between adjacent membranes in an electrodialysis stack having an electrode with a recessed edge and a total number of electrodialysis cell pairs (total cp), the spacer defining apertures therein for forming a distribution manifold that includes manifold ducts of a concentrated stream when the spacer is a part of the electrodialysis stack, the spacer comprising:
an impermeable membrane supporting area surrounding a flow field fluidly linking an inlet port and an outlet port;
electrically resistant structures positioned in the flow field proximate the inlet and outlet ports, and having a thickness equal to the thickness of the membrane supporting area;
wherein, when the spacer is positioned between the adjacent membranes in the electrodialysis stack:
i) the electrically resistant structures contact each of the adjacent membranes to reduce the area on the adjacent membranes available for an electrically conductive fluid connection, and;
(ii) the electrically resistant structures make up about 50% to about 75% of the surface area of the flow field from the inlet and outlet ports to a line spaced from the recessed edge of the electrode in a direction away from the inlet and outlet ports by an overlap distance that is about equal to:
(0.062 cm−1)*(exp(−60/total cp)*(area in cm2 of the manifold ducts of the concentrated stream at the recessed edge).
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