US 12,129,363 B2
Polyethylene-based compositions and films and articles comprising the same
Andrew T. Heitsch, Angleton, TX (US); Sanjib Biswas, Manvel, TX (US); Mridula Kapur, Lake Jackson, TX (US); Alexander Williamson, Rosharon, TX (US); Philip P. Fontaine, Pearland, TX (US); Joshua B. Gaubert, Pearland, TX (US); Daniel W. Baugh, III, Lake Jackson, TX (US); Jin Wang, Midland, MI (US); Didem Oner-Deliormanli, Bellaire, TX (US); Hitendra K. Singh, Missouri City, TX (US); Shadid Askar, Houston, TX (US); Arnaldo T. Lorenzo, Tarragona (ES); Mehmet Demirors, Pearland, TX (US); and Vivek Kalihari, Missouri City, TX (US)
Assigned to Dow Global Technologies LLC, Midland, MI (US)
Appl. No. 17/432,449
Filed by Dow Global Technologies LLC, Midland, MI (US)
PCT Filed May 1, 2020, PCT No. PCT/US2020/031151
§ 371(c)(1), (2) Date Aug. 19, 2021,
PCT Pub. No. WO2020/223688, PCT Pub. Date Nov. 5, 2020.
Claims priority of provisional application 62/842,253, filed on May 2, 2019.
Prior Publication US 2022/0056250 A1, Feb. 24, 2022
This patent is subject to a terminal disclaimer.
Int. Cl. C08L 23/06 (2006.01); C08K 3/36 (2006.01); C08K 5/098 (2006.01)
CPC C08L 23/06 (2013.01) [C08K 3/36 (2013.01); C08K 5/098 (2013.01); C08L 2201/14 (2013.01); C08L 2203/16 (2013.01); C08L 2205/025 (2013.01)] 10 Claims
 
1. A polyethylene-based composition suitable for packaging applications comprising:
(a) at least 97% by weight, based on the total weight of the polyethylene-based composition, of a polyethylene composition comprising:
(i) from 25 to 37 percent by weight of a first polyethylene fraction having a density in the range of 0.935 to 0.947 g/cm3 and a melt index (I2) of less than 0.1 g/10 minutes; and
(ii) from 63 to 75 percent by weight of a second polyethylene fraction; and
(b) 90 to 540 ppm, based on the total weight of the polyethylene-based composition of a calcium salt of 1,2-cyclohexanedicarboxylic acid;
wherein the polyethylene composition has less than 0.10 branches per 1,000 carbon atoms when measured using 13C NMR, wherein the density of the polyethylene-based composition is at least 0.965 g/cm3, and wherein the melt index (I2) of the polyethylene-based composition is 0.5 to 10 g/10 minutes.