US 12,127,558 B2
Solid formulation of insecticidal mixtures
Holger Egger, Cologne (DE); Reiner Fischer, Monheim (DE); Klaus Purbs, Lindlar (DE); and Ramona Schiffer, Leverkusen (DE)
Assigned to Bayer Aktiengesellschaft, Leverkusen (DE); and Bayer CropScience Aktiengesellschaft, Monheim am Rhein (DE)
Appl. No. 17/046,477
Filed by Bayer Aktiengesellschaft, Leverkusen (DE); and Bayer CropScience Aktiengesellschaft, Monheim am Rhein (DE)
PCT Filed Apr. 12, 2019, PCT No. PCT/EP2019/059471
§ 371(c)(1), (2) Date Oct. 9, 2020,
PCT Pub. No. WO2019/197631, PCT Pub. Date Oct. 17, 2019.
Claims priority of application No. 18167281 (EP), filed on Apr. 13, 2018.
Prior Publication US 2021/0161128 A1, Jun. 3, 2021
Int. Cl. A01N 25/14 (2006.01); A01N 25/30 (2006.01); A01N 43/90 (2006.01); A01N 59/26 (2006.01)
CPC A01N 25/14 (2013.01) [A01N 25/30 (2013.01); A01N 43/90 (2013.01); A01N 59/26 (2013.01)] 18 Claims
 
1. Solid composition in the form of water-dispersible granules comprising:
a) tetramic acid derivative of formula (I-2)

OG Complex Work Unit Chemistry
b) 20% to 65% by weight of diammonium hydrogenphosphate (DAHP),
c) 1% to 20% by weight of at least one dispersant selected from the group consisting of polyacrylic acid, polymethacrylic acid, polymaleic acid, polymaleic anhydride, a copolymer of maleic acid or maleic anhydride with an olefin, a copolymer of acrylic acid and itaconic acid, a copolymer of methacrylic acid and itaconic acid, a copolymer of acrylic acid and methacrylic acid, a copolymer of acrylic acid and methacrylate, a copolymer of acrylic acid and vinyl acetate, a copolymer of methacrylic acid and styrene, a modified copolymer of methacrylic acid and styrene, a copolymer of maleic acid or maleic anhydride and acrylic acid, an N-methyl fatty acid-sarcosinate, and salts thereof,
d) 0.5% to 15% by weight of at least one wetting agent selected from the group consisting of sodium salts of alkylated naphthalenesulfonates and sodium salts of dioctylsufosuccinic acid,
e) 10% to 70% by weight of at least one filler which is a silicate,
f) 0.5% to 15% by weight of at least one structure former selected from the group consisting of crosslinked polyureas, polyurethanes, and derivatized polyureas and polyurethanes,
g) optionally a complexing agent,
h) optionally one or more further active ingredients, and
i) optionally one or more further adjuvants and formulation auxiliaries.