US 12,454,593 B2
Composition for self-adhesive foamed sheet and self-adhesive foamed laminate sheet
Shunsuke Nishimura, Tokyo (JP); and Shinsuke Ashida, Tokyo (JP)
Assigned to ZEON CORPORATION, Tokyo (JP)
Appl. No. 17/759,756
Filed by ZEON CORPORATION, Tokyo (JP)
PCT Filed Feb. 15, 2021, PCT No. PCT/JP2021/005572
§ 371(c)(1), (2) Date Jul. 29, 2022,
PCT Pub. No. WO2021/166861, PCT Pub. Date Aug. 26, 2021.
Claims priority of application No. 2020-026398 (JP), filed on Feb. 19, 2020.
Prior Publication US 2023/0078720 A1, Mar. 16, 2023
This patent is subject to a terminal disclaimer.
Int. Cl. C08F 283/06 (2006.01); C08J 9/00 (2006.01)
CPC C08F 283/06 (2013.01) [C08J 9/0061 (2013.01); C08J 2333/08 (2013.01); C08J 2491/06 (2013.01)] 4 Claims
 
1. A self-adhesive foamed laminate sheet comprising
a substrate wherein the substrate is a plastic substrate, a fiber substrate, a metal substrate, a glass substrate or a paper substrate other than a synthetic paper substrate; and
a self-adhesive foamed sheet in the form of a single layer that is directly attached to the substrate, the self-adhesive foam sheet being formed from the composition comprising a polymer, a crosslinking agent, and a wax agent, wherein
a gel fraction of the polymer is 80% or more,
the polymer consists of 60 mass % or more and 99 mass % or less of a (meth)acrylate monomer unit, 0.1 mass % or more and 10 mass % or less of an unsaturated carboxylic acid monomer unit, 1 mass % or more and 30 mass % or less of a vinyl cyanide monomer unit, and 0.5 mass % or more and 20 mass % or less of an alkenyl aromatic monomer unit, based on 100 mass % of the polymer, and wherein the polymer is free of N-methylol groups,
the crosslinking agent is at least one selected from the group consisting of a fatty acid polyglycidyl ether, glycerol polyglycidyl ether, and ethylene glycol diglycidyl ether, a blending amount of the crosslinking agent in the composition is 0.5 parts by mass or more and 20 parts by mass or less per 100 parts by mass of the polymer,
the wax agent is at least one selected from the group consisting of sugarcane wax, jojoba oil, wood wax, Moringa pterygosperma seed oil and ozokerite, a blending amount of the wax agent in the composition is 0.5 parts by mass or more and 10 parts by mass or less per 100 parts by mass of the polymer, and
wherein the self-adhesive foamed laminate sheet has an ability to adhere repeatedly to surfaces and to be released repeatedly from the surfaces without leaving a trace thereof on the surfaces.