US 12,453,153 B2
Work-function layers in the gates of pFETs
Hsin-Yi Lee, Hsinchu (TW); Yen-Tien Tung, Hsinchu (TW); Ji-Cheng Chen, Hsinchu (TW); Weng Chang, Hsinchu (TW); and Chi On Chui, Hsinchu (TW)
Assigned to Taiwan Semiconductor Manufacturing Co., Ltd., Hsinchu (TW)
Filed by Taiwan Semiconductor Manufacturing Co., Ltd., Hsinchu (TW)
Filed on Jun. 1, 2022, as Appl. No. 17/804,971.
Claims priority of provisional application 63/268,876, filed on Mar. 4, 2022.
Prior Publication US 2023/0282712 A1, Sep. 7, 2023
Int. Cl. H10D 64/01 (2025.01); H01L 21/28 (2006.01); H10D 30/01 (2025.01); H10D 30/67 (2025.01); H10D 84/83 (2025.01)
CPC H10D 64/01 (2025.01) [H01L 21/28088 (2013.01); H10D 30/031 (2025.01); H10D 30/6739 (2025.01); H10D 64/017 (2025.01); H10D 84/83 (2025.01); H10D 30/6757 (2025.01)] 20 Claims
OG exemplary drawing
 
1. A method comprising:
forming a dummy gate stack over a semiconductor region;
forming a source/drain region on a side of the dummy gate stack;
removing the dummy gate stack to form a trench, with the semiconductor region being exposed to the trench;
forming a gate dielectric layer extending into the trench;
depositing a work-function tuning layer on the gate dielectric layer, wherein the work-function tuning layer comprises aluminum and carbon, and the depositing the work-function tuning layer comprises thermal soaking processes using a first process gas comprising aluminum, and a second process gas comprising carbon;
depositing a p-type work-function layer over the work-function tuning layer; and
performing a planarization process to remove excess portions of the p-type work-function layer, the work-function tuning layer, and the gate dielectric layer to form a gate stack.