| CPC G03F 7/168 (2013.01) [C23C 14/086 (2013.01); C23C 16/407 (2013.01); C23C 16/45523 (2013.01); C23C 16/45561 (2013.01); G03F 7/0042 (2013.01); G03F 7/0043 (2013.01); G03F 7/162 (2013.01); G03F 7/167 (2013.01); G03F 7/2004 (2013.01); G03F 7/30 (2013.01); G03F 7/325 (2013.01); G03F 7/38 (2013.01); G03F 7/40 (2013.01)] | 31 Claims |

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1. A method for forming a radiation patternable organometallic film on a substrate, the method comprising:
inputting into a deposition chamber closed from the ambient atmosphere a first precursor vapor comprising an organotin composition having at least one Sn—C bond and having at least one ligand having a hydrolysable bond with Sn; and
forming the radiation patternable organometallic film on the substrate, wherein the radiation patternable organometallic film comprises C—Sn bonds and has an average film thickness from about 1 nm to about 50 nm, and wherein the radiation patternable organometallic film comprises an oxo-hydroxo network.
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