| CPC G01N 27/3272 (2013.01) [C12N 9/0006 (2013.01); C12Q 1/004 (2013.01); C12Q 1/006 (2013.01); G01N 27/3271 (2013.01); G01N 27/3274 (2013.01); G01N 33/492 (2013.01); C12Y 101/0103 (2013.01); G01N 2800/042 (2013.01)] | 12 Claims |

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1. An amperometric analyte sensor system comprising:
a 3-hydroxybutyrate sensing electrode comprising:
a layer of an electroactive material;
an enzyme layer comprising 3-hydroxybutyrate dehydrogenase enzyme in operable contact with the electroactive material, wherein the 3-hydroxybutyrate dehydrogenase enzyme comprises SEQ ID NO: 1 or SEQ ID NO: 2;
a nicotinamide adenine dinucleotide in operable contact with the 3-hydroxybutyrate dehydrogenase enzyme;
a mediator in operable contact with the nicotinamide adenine dinucleotide; and
a 3-hydroxybutyrate modulating layer disposed over the enzyme layer, wherein the 3-hydroxybutyrate modulating layer comprises a composition that modulates diffusion of 3-hydroxybutyrate through the 3-hydroxybutyrate modulating layer.
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