US 12,442,105 B2
Nanowires network
Juan José Vilatela García, Getafe (ES); and Richard Santiago Schäufele, Getafe (ES)
Assigned to FUNDACIÓN IMDEA MATERIALES, Madrid (ES)
Appl. No. 17/755,937
Filed by FUNDACIÓN IMDEA MATERIALES, Getafe (ES)
PCT Filed Nov. 12, 2020, PCT No. PCT/EP2020/081963
§ 371(c)(1), (2) Date May 12, 2022,
PCT Pub. No. WO2021/094485, PCT Pub. Date May 20, 2021.
Claims priority of application No. 19382996 (EP), filed on Nov. 13, 2019.
Prior Publication US 2022/0389614 A1, Dec. 8, 2022
Int. Cl. C30B 11/12 (2006.01); B82Y 40/00 (2011.01); C30B 11/14 (2006.01); C30B 25/00 (2006.01); C30B 29/08 (2006.01); C30B 29/62 (2006.01)
CPC C30B 29/62 (2013.01) [B82Y 40/00 (2013.01); C30B 11/12 (2013.01); C30B 11/14 (2013.01); C30B 25/005 (2013.01); C30B 29/08 (2013.01)] 19 Claims
OG exemplary drawing
 
1. A method for preparing a network of nanowires comprising the steps of:
i. providing a first gas flow to a reaction vessel;
wherein said first gas flow comprises at least one precursor compound comprising at least one element selected from Si, Ge, Al, Cu, Zn, Pt, Mo, W, Mn, and Li; wherein the at least one precursor compound is a metallic hydride or an organometallic compound; and
ii. providing a second gas flow to the reaction vessel, said second gas flow comprising metallic catalyst particles; wherein the metallic catalyst particles consist of one element selected from Au, Ag, Cu, Fe, Ni, Ga, Co, Pt, In and Al; so as the first and second gas flows are mixed in the reaction vessel to form a gas flow mixture consisting of:
the at least one precursor compound,
at least a sheath gas selected from nitrogen, hydrogen and/or noble gases, and
the metallic catalyst particles;
wherein the precursor compound or the sum of precursor compounds is in the gas flow mixture in a mole fraction (xi) of between 0.006 and 0.50;
wherein the temperature inside the reaction vessel ranges from 200 to 800° C. or is at least 801° C.; and
wherein the at least one precursor compound decomposes under the temperature inside the reaction vessel and grows on the metallic catalyst particles by vapor liquid-solid (VLS) and/or chemical vapor deposition (CVD) to form a network of nanowires;
wherein the nanowires of the network of nanowires are made of a solid material or are hollow.