| CPC C23C 16/40 (2013.01) [C23C 16/45553 (2013.01)] | 14 Claims |

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1. A method of forming a coated article, the method comprising:
providing an article adapted for use in a processing chamber, the article having a first coefficient of thermal expansion;
forming an amorphous carbon adhesion layer on one or more surfaces of the article;
selecting a molar ratio of a first rare earth metal-containing ceramic compound to a second rare earth metal-containing ceramic compound, such that a ceramic coating comprising the first and second rare earth metal-containing ceramic compounds in the selected molar ratio being deposited onto the carbon adhesion layer by atomic layer deposition results in the ceramic coating having a second coefficient of thermal expansion that is within 10% of the first coefficient of thermal expansion; and
performing atomic layer deposition to simultaneously deposit both the first rare earth metal-containing ceramic compound and the second rare earth metal-containing ceramic compound onto the carbon adhesion layer, wherein the first rare earth metal-containing ceramic compound comprises Y2O3, and the second rare earth metal-containing ceramic compound comprises YxOyFz.
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