US 12,441,828 B2
Radiation-curable composition for use in rapid prototyping or rapid manufacturing methods
Alfred Hohmann, Schmitten (DE)
Assigned to Kulzer GmbH, Hanau (DE)
Filed by KULZER GMBH, Hanau (DE)
Filed on Feb. 23, 2024, as Appl. No. 18/585,324.
Application 18/585,324 is a division of application No. 17/437,301, granted, now 11,939,414, previously published as PCT/EP2020/056346, filed on Mar. 10, 2020.
Claims priority of application No. 10 2019 106 152.0 (DE), filed on Mar. 11, 2019.
Prior Publication US 2024/0317918 A1, Sep. 26, 2024
This patent is subject to a terminal disclaimer.
Int. Cl. C08F 2/46 (2006.01); A61C 13/00 (2006.01); A61K 6/62 (2020.01); A61K 6/893 (2020.01); B33Y 70/00 (2020.01); C08F 2/50 (2006.01); C08F 283/06 (2006.01); C08G 61/04 (2006.01); B29C 64/124 (2017.01); B29K 33/00 (2006.01)
CPC C08F 283/06 (2013.01) [A61C 13/0019 (2013.01); A61C 13/0022 (2013.01); A61K 6/62 (2020.01); A61K 6/893 (2020.01); B33Y 70/00 (2014.12); B29C 64/124 (2017.08); B29K 2033/12 (2013.01); B29K 2995/0077 (2013.01); B29K 2995/0082 (2013.01)] 22 Claims
 
1. Polymerisable radiation-curable composition comprising
(i) monomers and
(ii) at least one further component,
wherein
(i) the monomers comprise at least
 (a) one first monomer having a TG (glass-transition point) of the homopolymer of said first monomer of greater than or equal to 120° C. comprising
 di-functional acrylates having a bivalent alicyclic group and/or di-functional methacrylates having a bivalent alicyclic group and
at least one di-functional urethane (meth)acrylate selected from di-functional urethane (meth)acrylates having a bivalent alkylene group,
and at least
(b) one second monomer having a TG (glass-transition point) of the homopolymer of the second monomer of less than or equal to 100° C. comprising
 at least one mono-functional acrylate having an alicyclic group and/or mono-functional methacrylate having an alicyclic group, and
(ii) the at least one further component comprises at least one photo-initiator for the UV and/or Vis spectral region or a photo-initiator system for the UV and/or Vis spectral region, wherein the viscosity of the composition at approx. 20° C. to 23° C. is less than or equal to 3000 m·Pas.