US 12,110,385 B2
Chlorinated vinyl chloride resin
Kenichi Matsumura, Yamaguchi (JP); Norikazu Mashino, Yamaguchi (JP); Kento Murakami, Yamaguchi (JP); Nami Nakajima, Osaka (JP); Yasunari Kusaka, Osaka (JP); Takehisa Sugaya, Yamaguchi (JP); and Masahiko Yamagata, Tokyo (JP)
Assigned to SEKISUI CHEMICAL CO., LTD., Osaka (JP); and TOKUYAMA SEKISUI CO., LTD., Osaka (JP)
Appl. No. 17/436,910
Filed by SEKISUI CHEMICAL CO., LTD., Osaka (JP); and TOKUYAMA SEKISUI CO., LTD., Osaka (JP)
PCT Filed Mar. 27, 2020, PCT No. PCT/JP2020/014241
§ 371(c)(1), (2) Date Sep. 7, 2021,
PCT Pub. No. WO2020/203858, PCT Pub. Date Oct. 8, 2020.
Claims priority of application No. 2019-068512 (JP), filed on Mar. 29, 2019; and application No. 2019-204831 (JP), filed on Nov. 12, 2019.
Prior Publication US 2022/0145061 A1, May 12, 2022
Int. Cl. C08F 8/22 (2006.01); C08L 27/24 (2006.01)
CPC C08L 27/24 (2013.01) [C08F 8/22 (2013.01); C08L 2201/08 (2013.01); C08L 2203/30 (2013.01)] 10 Claims
 
1. A chlorinated polyvinyl chloride resin,
comprising three components including a A150 component, a B150 component, and a C150 component, and
having a percentage of the C150 component (C150 component/(A150 component+B150 component+C150 component)) of 8.0% or more and 50.0% or less,
the three components being identified by measuring the chlorinated polyvinyl chloride resin by a solid echo method using pulse NMR at 150° C. to give a free induction decay curve of 1H spin-spin relaxation, and subjecting the free induction decay curve to waveform separation into three curves derived from the A150 component, the B150 component, and the C150 component in order of shorter relaxation time using the least square method,
wherein the chlorinated polyvinyl chloride resin has a degree of polymerization of 100 to 2,000, and
wherein the chlorinated polyvinyl chloride resin contains units (a) to (c) represented by the following formulas (a) to (c), and a proportion of the structural unit (a) is 5.0 mol % or higher and 90.0 mol % or lower, a proportion of the structural unit (b) is 5.0 mol % or higher and 40.0 mol % or lower, and a proportion of the structural unit (c) is 5.0 mol % or higher and 55.0 mol % or lower, relative to total number of moles of the structural units (a), (b), and (c)
—CH2—CHCl—  (a)
—CH2—CCl2—  (b)
—CHCl—CHCl—  (c).