US 12,110,366 B2
Semi-aromatic, semi-crystalline polyamide polymers and corresponding polymer compositions and articles
Joel W. Flores, Alpharetta, GA (US); and Stéphane Jeol, Saint-Genis-Laval (FR)
Assigned to SOLVAY SPECIALTY POLYMERS USA, LLC, Alpharetta, GA (US)
Appl. No. 17/424,988
Filed by SOLVAY SPECIALTY POLYMERS USA, LLC, Alpharetta, GA (US)
PCT Filed Jan. 21, 2020, PCT No. PCT/EP2020/051444
§ 371(c)(1), (2) Date Jul. 22, 2021,
PCT Pub. No. WO2020/152185, PCT Pub. Date Jul. 30, 2020.
Claims priority of provisional application 62/795,324, filed on Jan. 22, 2019.
Claims priority of application No. 19157834 (EP), filed on Feb. 18, 2019.
Prior Publication US 2022/0127420 A1, Apr. 28, 2022
Int. Cl. C08G 69/26 (2006.01); C08K 3/32 (2006.01)
CPC C08G 69/265 (2013.01) [C08K 3/32 (2013.01); C08K 2003/329 (2013.01)] 11 Claims
 
1. A polymer comprising recurring units RPA1, RPA2, RPA3, RPA4,
wherein
a) recurring unit RPA1 is represented by the following formula:

OG Complex Work Unit Chemistry
wherein
R1 and R2, at each location, is independently selected from the group consisting of a hydrogen, a halogen, an alkenyl, an alkynyl, on aryl, an ether, a thioether, a carboxylic acid, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine, and a quaternary ammonium, and
R3 to R6 are independently selected from the group consisting of a hydrogen, a halogen, an alkyl, an alkenyl, an alkynyl, an aryl, an ether, a thioether, a carboxylic acid, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine, and a quaternary ammonium;
b) Recurring unit RPA2 is represented by a formula selected from the following group of formulae:

OG Complex Work Unit Chemistry
Wherein R7 to R10, at each location, and R11 to R24 are independently selected from the group consisting of a hydrogen, a halogen, an alkyl, an alkenyl, an alkynyl, an aryl, an ether, a thioether, a carboxylic acid, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine, and a quaternary ammonium; and n1 and n2 are independently selected integers from 1 to 10;
c) recurring unit RPA3 is distinct from recurring unit RPA1 and represented by Formula (1) or the following

OG Complex Work Unit Chemistry
 formula:
d) recurring unit RPA4 is distinct from recurring unit RPA2 and is represented by a formula selected from Formulae (3) to (6).