US 11,780,738 B2
Production of calcium hydroxide nanoparticles and their use as accelerators in mineral binder compositions
Patrick Juilland, Bern (CH); Emmanuel Gallucci, Zürich (CH); Denise Schönenberger, Kollbrunn (CH); Luis Pegado, Brugg (CH); Lukas Frunz, Dietlikon (CH); and Arnd Eberhardt, Winterthur (CH)
Assigned to SIKA TECHNOLOGY AG, Baar (CH)
Appl. No. 16/976,704
Filed by SIKA TECHNOLOGY AG, Baar (CH)
PCT Filed Mar. 22, 2019, PCT No. PCT/EP2019/057201
§ 371(c)(1), (2) Date Aug. 28, 2020,
PCT Pub. No. WO2019/180191, PCT Pub. Date Sep. 26, 2019.
Claims priority of application No. 18163482 (EP), filed on Mar. 22, 2018.
Prior Publication US 2021/0053837 A1, Feb. 25, 2021
Int. Cl. C01F 11/02 (2006.01); C04B 40/00 (2006.01); C04B 22/06 (2006.01); C04B 24/26 (2006.01); B82Y 40/00 (2011.01); C04B 103/12 (2006.01)
CPC C01F 11/02 (2013.01) [C04B 22/064 (2013.01); C04B 24/2647 (2013.01); C04B 40/0039 (2013.01); B82Y 40/00 (2013.01); C01P 2004/51 (2013.01); C01P 2004/62 (2013.01); C01P 2006/22 (2013.01); C04B 2103/12 (2013.01)] 15 Claims
OG exemplary drawing
 
1. A method for producing an aqueous suspension, comprising: (a) providing an aqueous solution A comprising at least 5 weight % of a water-soluble calcium salt, (b) providing an aqueous solution B comprising at least 5 weight % of an alkali metal hydroxide, (c) metering solution A and solution B simultaneously into a continuous reactor and contacting solution A and solution B such that solution A and solution B are mixed rapidly and intensely to form a suspension, wherein the rapid and intense mixing of the solution A and the solution B takes place continuously and a mixing time is below 1 minute, wherein the solution A and solution B are metered under pressure of at least 5 bar into the continuous reactor by means of pumps, wherein the pressure and a resulting velocity of the solution A and the solution B on introduction into the continuous reactor produces the rapid and intense mixing, and (d) discharging the suspension from the continuous reactor, where a compound for stabilizing the suspension is added to the solution A, to the solution B or to both solutions, or to the suspension produced, wherein the suspension includes calcium hydroxide in the form of nanoparticles having a particle size D90 of below 800 nm, measured by dynamic light scattering with photon cross-correlation spectroscopy, and wherein the suspension is free from calcium silicate hydrate.