US 12,438,041 B2
Interconnect structure and method of forming the same
Wei-Ren Wang, New Taipei (TW); Jen Hung Wang, Zhubei (TW); and Tze-Liang Lee, Hsinchu (TW)
Assigned to Taiwan Semiconductor Manufacturing Co., Ltd., Hsinchu (TW)
Filed by Taiwan Semiconductor Manufacturing Co., Ltd., Hsinchu (TW)
Filed on Apr. 14, 2022, as Appl. No. 17/720,899.
Prior Publication US 2023/0335436 A1, Oct. 19, 2023
Int. Cl. H01L 21/768 (2006.01); H01L 23/522 (2006.01); H01L 23/532 (2006.01)
CPC H01L 21/76832 (2013.01) [H01L 23/5226 (2013.01); H01L 23/5329 (2013.01)] 20 Claims
OG exemplary drawing
 
1. A method of manufacturing a semiconductor device, the method comprising:
forming a first interconnect level over a substrate, the first interconnect level comprising a dielectric layer and a first conductive feature through the dielectric layer;
depositing an inhibitor cap on a top surface of the first conductive feature, wherein a top surface of the dielectric layer remains exposed after depositing the inhibitor cap;
forming an etch-resistant layer on the top surface of the dielectric layer, wherein a top surface of the inhibitor cap remains exposed after forming the etch-resistant layer;
depositing an etch stop layer (ESL) over the etch-resistant layer and the inhibitor cap;
removing the inhibitor cap with a plasma treatment, wherein after removing the inhibitor cap, an air gap remains between the first conductive feature and the ESL; and
forming a second interconnect level over the first interconnect level, wherein a conductive via of the second interconnect level extends through the ESL to the top surface of the first conductive feature.