US 12,107,226 B2
Electrolyte for power storage devices and nonaqueous electrolyte solution
Tailu Ning, Kamisu (JP); Kazuyuki Shimizu, Kamisu (JP); and Hiroo Nitta, Kamisu (JP)
Assigned to TOMIYAMA PURE CHEMICAL INDUSTRIES, LTD., Tokyo (JP)
Filed by TOMIYAMA PURE CHEMICAL INDUSTRIES, LTD., Tokyo (JP)
Filed on Oct. 19, 2023, as Appl. No. 18/381,688.
Application 18/381,688 is a continuation of application No. 16/981,798, granted, now 11,830,982, previously published as PCT/JP2018/011832, filed on Mar. 23, 2018.
Prior Publication US 2024/0088444 A1, Mar. 14, 2024
This patent is subject to a terminal disclaimer.
Int. Cl. H01M 10/0568 (2010.01); C01B 33/32 (2006.01); C01B 35/10 (2006.01); C01B 35/14 (2006.01); H01G 11/60 (2013.01); H01G 11/62 (2013.01); H01G 11/64 (2013.01); H01M 10/0525 (2010.01); H01M 10/0567 (2010.01); H01M 10/0569 (2010.01)
CPC H01M 10/0568 (2013.01) [C01B 33/32 (2013.01); C01B 35/1027 (2013.01); C01B 35/14 (2013.01); C01B 35/146 (2013.01); H01G 11/60 (2013.01); H01G 11/62 (2013.01); H01G 11/64 (2013.01); H01M 10/0525 (2013.01); H01M 10/0567 (2013.01); H01M 10/0569 (2013.01); C01P 2006/40 (2013.01); H01M 2300/004 (2013.01)] 12 Claims
 
1. An electrolytic solution for a storage device, which comprises a solvent and a lithium-containing complex compound represented by the following formula (1), (2), (3), (4) or (5):
(Li)m(A)n(UFx)y  (1)
(Li)m(Si)n(O)q(UFx)y  (2)
wherein A is O, S, P or N; U is a boron atom or a phosphorus atom; m and n are each independently from 1 to 6; q is from 1 to 12; x is 3 or 5; and y is from 1 to 6;
(Li)m(O)n(B)p(OWFq)x  (3)
wherein W is a boron atom or a phosphorus atom; m, p and x are each independently from 1 to 15; n is from 0 to 15; and q is 3 or 5;
(Li)m(B)p(O)n(OR)y(OWFq)x  (4)
wherein W is a boron atom or a phosphorus atom; n is from 0 to 15; p, m, x and y are each independently from 1 to 12; q is 3 or 5; and R is hydrogen, an alkyl group, an alkenyl group, an aryl group, a carbonyl group, a sulfonyl group or a silyl group, and such a group may have a fluorine atom, an oxygen atom or other substituent;
(Li)m(O)n(B)p(OOC-(A)z-COO)y(OWFq)x  (5)
wherein W is a boron atom or a phosphorus atom, A is a C1-6 allylene group, alkenylene group or alkynylene group, a phenylene group, or an alkylene group having an oxygen atom or a sulfur atom in its main chain; m, p, x and y are each independently from 1 to 20; n is from 0 to 15; z is 0 or 1; and q is 3 or 5.