US 12,104,042 B2
Plasticizer composition and vinyl chloride-based resin composition including the same
Myung-Ik Yoo, Daejeon (KR); Jae Song Kim, Daejeon (KR); Sung Min Ryoo, Seoul (KR); and Ki Jo Sim, Daejeon (KR)
Assigned to HANWHA SOLUTIONS CORPORATION, Seoul (KR)
Appl. No. 17/295,906
Filed by Hanwha Solutions Corporation, Seoul (KR)
PCT Filed Oct. 18, 2019, PCT No. PCT/KR2019/013763
§ 371(c)(1), (2) Date May 21, 2021,
PCT Pub. No. WO2020/130315, PCT Pub. Date Jun. 25, 2020.
Claims priority of application No. 10-2018-0167915 (KR), filed on Dec. 21, 2018.
Prior Publication US 2022/0010096 A1, Jan. 13, 2022
Int. Cl. C08K 5/11 (2006.01); C08K 5/12 (2006.01); C08L 27/06 (2006.01)
CPC C08K 5/11 (2013.01) [C08K 5/12 (2013.01); C08L 27/06 (2013.01); C08L 2201/10 (2013.01)] 6 Claims
 
1. A vinyl chloride-based resin composition comprising a vinyl chloride-based resin, and a plasticizer composition comprising di(2-ethylhexyl)cyclohexane-1,4-dicarboxylate and di(2-ethylhexyl)adipate, and wherein a weight ratio of di(2-ethylhexyl)cyclohexane-1,4-dicarboxylate and di(2-ethylhexyl)adipate is 95:5 to 50:50 and wherein the resin has low temperature brittleness (LTB) is −41° C. or lower, as measured according to ASTM D746, haze is 9% or less, as measured according to ASTM D1003, and wherein the plastic migration is 0.48% or lower, as measured by placing oil-absorbing paper made of polypropylene on the top/bottom of a circular specimen with a thickness of 2 mm and a diameter of about 4 cm, and leaving at 60° C. for 7 days under a load of 5 kg to promote plasticizer migration, and then calculating the weight change rate of the specimen according to [(weight change of specimen/weight of specimen before test)*100].