US 12,103,988 B2
Gas-phase process for preparing ethylene polymers
Giuseppe Penzo, Ferrara (IT); Gerhardus Meier, Houston, TX (US); Ulf Schueller, Weiterstadt (DE); Pietro Baita, Ferrara (IT); Giulia Mei, Ferrara (IT); and Elke Damm, Bad Vilbel (DE)
Assigned to Basell Polyolefine GmbH, Wesseling (DE)
Appl. No. 17/312,822
Filed by Basell Polyolefine GmbH, Wesseling (DE)
PCT Filed Dec. 16, 2019, PCT No. PCT/EP2019/085422
§ 371(c)(1), (2) Date Jun. 10, 2021,
PCT Pub. No. WO2020/127098, PCT Pub. Date Jun. 25, 2020.
Claims priority of application No. 18213407 (EP), filed on Dec. 18, 2018.
Prior Publication US 2021/0332167 A1, Oct. 28, 2021
Int. Cl. C08F 210/16 (2006.01); B01J 8/00 (2006.01); B01J 8/18 (2006.01); B01J 8/26 (2006.01); B01J 21/04 (2006.01); B01J 23/42 (2006.01); B01J 23/44 (2006.01); B01J 23/72 (2006.01); C08F 2/01 (2006.01); C08F 2/34 (2006.01); C08F 110/02 (2006.01)
CPC C08F 110/02 (2013.01) [B01J 8/0055 (2013.01); B01J 8/1827 (2013.01); B01J 8/1863 (2013.01); B01J 8/1881 (2013.01); B01J 8/26 (2013.01); B01J 21/04 (2013.01); B01J 23/42 (2013.01); B01J 23/44 (2013.01); B01J 23/72 (2013.01); C08F 210/16 (2013.01); C08F 2/01 (2013.01); C08F 2/34 (2013.01)] 20 Claims
OG exemplary drawing
 
1. A process for the preparation of an ethylene polymer, comprising a step of
forming an ethylene polymer in particle form in a gas-phase polymerization unit comprising a gas-phase polymerization reactor by homopolymerizing ethylene or copolymerizing ethylene and one or more C4-C12-1-alkenes at temperatures from 20 to 200° C. and pressures of from 0.5 to 10 MPa in a reaction gas comprising propane as polymerization diluent in the presence of a polymerization catalyst,
wherein a purified propane feed stream comprising at least 99% mol propane and not more than 100 ppm-mol propylene is fed into the gas-phase polymerization unit and purification of the purified propane feed stream has been carried out by passing a hydrocarbon stream containing propane, propylene, acetylene, carbon monoxide, carbon dioxide, oxygen and water through hydrocarbon purification units which reduce at least a concentration of propylene, acetylene, carbon monoxide, carbon dioxide, oxygen and water contained in the hydrocarbon stream to produce the purified propane feed stream.