US 12,102,984 B2
Green method for preparing jute stem-supported catalyst
M. Nasiruzzaman Shaikh, Dhahran (SA)
Assigned to KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS, Dhahran (SA)
Filed by KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS, Dhahran (SA)
Filed on Mar. 15, 2024, as Appl. No. 18/606,738.
Application 17/929,166 is a division of application No. 16/732,579, filed on Jan. 2, 2020, granted, now 11,471,861, issued on Oct. 18, 2022.
Application 18/606,738 is a continuation of application No. 17/929,166, filed on Sep. 1, 2022, granted, now 11,980,870.
Prior Publication US 2024/0278216 A1, Aug. 22, 2024
This patent is subject to a terminal disclaimer.
Int. Cl. B01J 23/44 (2006.01); B01J 31/06 (2006.01); B01J 35/30 (2024.01); B01J 35/40 (2024.01); B01J 37/04 (2006.01); B01J 37/08 (2006.01); B01J 37/16 (2006.01); C07C 1/26 (2006.01)
CPC B01J 23/44 (2013.01) [B01J 31/06 (2013.01); B01J 35/393 (2024.01); B01J 35/40 (2024.01); B01J 37/04 (2013.01); B01J 37/08 (2013.01); B01J 37/16 (2013.01); C07C 1/26 (2013.01); B01J 2231/4211 (2013.01); B01J 2231/4261 (2013.01); C07C 2523/44 (2013.01)] 16 Claims
 
1. A green method of preparing a palladium catalyst supported on jute stem materials, the method comprising:
mixing a particulate matrix, comprising α-cellulose, hemicellulose, and lignin, with a palladium compound in an aqueous solution to form a suspension, wherein the α-cellulose, the hemicellulose, and the lignin are entirely obtained from jute stems;
combining the suspension with a reducing agent to form a mixture; and
heating the mixture to thereby reduce at least 50 wt. % of the palladium compound, relative to total catalytic metal weight, and form the solid-supported palladium catalyst,
wherein the particles of the particulate matrix have no average dimension less than 10 μm, and
wherein the lignin is present in the particulate matrix in a range of from 15 to 30 wt. % relative to total particulate matrix weight.