US 12,102,958 B2
Method and apparatus for recovering absorbing agents in acid gas treatment
Ulises I. Cruz, Pearland, TX (US); Erik J. Stewart, Pearland, TX (US); and Rodrigo Zamora, Houston, TX (US)
Assigned to INEOS Americas, LLC, Mobile, AL (US)
Filed by Ineos Americas, LLC, Mobile, AL (US)
Filed on Sep. 2, 2022, as Appl. No. 17/902,385.
Application 17/902,385 is a continuation of application No. 16/871,110, filed on May 11, 2020, granted, now 11,433,347.
Application 16/871,110 is a continuation of application No. 15/641,980, filed on Jul. 5, 2017, granted, now 10,646,818, issued on May 12, 2020.
Claims priority of provisional application 62/365,666, filed on Jul. 22, 2016.
Claims priority of provisional application 62/358,397, filed on Jul. 5, 2016.
Prior Publication US 2023/0106908 A1, Apr. 6, 2023
This patent is subject to a terminal disclaimer.
Int. Cl. B01D 53/14 (2006.01); B01D 53/18 (2006.01); C10G 21/12 (2006.01); C10G 21/28 (2006.01); C10G 70/06 (2006.01); C10K 1/00 (2006.01); C10L 3/10 (2006.01)
CPC B01D 53/1425 (2013.01) [B01D 53/1456 (2013.01); B01D 53/1493 (2013.01); B01D 53/18 (2013.01); C10G 21/12 (2013.01); C10G 21/28 (2013.01); C10G 70/06 (2013.01); C10K 1/003 (2013.01); C10L 3/103 (2013.01); C10L 3/104 (2013.01); B01D 2252/20405 (2013.01); B01D 2252/2041 (2013.01); B01D 2252/504 (2013.01); C10G 2300/203 (2013.01); C10G 2300/207 (2013.01); C10G 2300/208 (2013.01); C10L 3/101 (2013.01); C10L 2290/541 (2013.01)] 20 Claims
OG exemplary drawing
 
1. A continuous process for acid gas removal comprising the following steps:
(a) introducing into an absorber having an absorber interior and an absorption zone located in the absorber interior a mixture of process gas and acid gas;
(b) counter-currently contacting in the absorption zone the mixture of process gas and acid gas referred to in step “a” with an absorbent chemical, and water, the absorbent chemical and water are in solution prior to contact and
(c) removing the process gas overhead from the absorption zone;
(d) removing the absorbent chemical and water solution with the acid gas absorbed therein from the bottom of the absorption zone;
(e) introducing the solution from step “d” into a regenerator having a regeneration interior and a regeneration zone located in the regeneration interior;
(f) separating a mixture of acid gas, absorbent chemical, and water from the solution referred to in step “e”, the separated absorbent chemical and water portion being in the form of vapor, and removing the separated mixture of acid gas, absorbent chemical, and water overhead from the regeneration zone;
(g) introducing the separated mixture of acid gas, absorbent chemical, and water referred to in step “f” to a static mixing zone not located in the regeneration interior, wherein the static mixing zone includes a static mixing device having a tubular casing with a longitudinal axis and at least one mixing element, wherein supplemental washing water is added and intimately mixed with the separated mixture of acid gas, absorbent chemical, and water referred to in step “f”, thereby creating a water washed separated mixture of acid gas, absorbent chemical, and water solution, and wherein the separated mixture of acid gas, absorbent chemical, and water solution and the supplemental washing water have co-current flows;
(h) passing the water washed separated mixture of acid gas, absorbent chemical, and water solution of step “g” into a cooling zone wherein the temperature of the water washed separated mixture is reduced;
(i) removing the balance of the solution referred to in step “f” from the bottom of the regeneration zone;
(j) passing the solution from step “i” into a cooling zone wherein the temperature of the solution is reduced; and
(k) recycling the solution of step “j” to the absorption zone, wherein in step “g” the at least one mixing element includes crossed webs disposed at an angle with the longitudinal axis, the webs being disposed in at least two groups, the webs of any one group of elements extending substantially parallel to one another and the webs of one group crossing the webs of the other group.