US 11,777,142 B2
Gelable system containing ether compounds, preparation method therefor and use thereof
Lin Li, Beijing (CN); Fengquan Liu, Beijing (CN); Jianjun Zhou, Beijing (CN); and Lu Wang, Beijing (CN)
Assigned to BEIJING NORMAL UNIVERSITY, Beijing (CN)
Filed by BEIJING NORMAL UNIVERSITY, Beijing (CN)
Filed on Nov. 26, 2019, as Appl. No. 16/696,510.
Application 16/696,510 is a continuation in part of application No. PCT/CN2018/088494, filed on May 25, 2018.
Claims priority of application No. 201710385201.1 (CN), filed on May 26, 2017; application No. 201710385203.0 (CN), filed on May 26, 2017; application No. 201710386733.7 (CN), filed on May 26, 2017; application No. 201710386734.1 (CN), filed on May 26, 2017; application No. 201710386736.0 (CN), filed on May 26, 2017; and application No. 201710386738.X (CN), filed on May 26, 2017.
Prior Publication US 2020/0099096 A1, Mar. 26, 2020
Int. Cl. H01M 10/0565 (2010.01); H01G 11/56 (2013.01); H01G 11/60 (2013.01); H01G 11/62 (2013.01); H01M 10/052 (2010.01); H01M 10/0568 (2010.01); H01M 10/0569 (2010.01); B82Y 30/00 (2011.01)
CPC H01M 10/0565 (2013.01) [H01G 11/56 (2013.01); H01G 11/60 (2013.01); H01G 11/62 (2013.01); H01M 10/052 (2013.01); H01M 10/0568 (2013.01); H01M 10/0569 (2013.01); B82Y 30/00 (2013.01); H01M 2300/0082 (2013.01); H01M 2300/0085 (2013.01)] 1 Claim
OG exemplary drawing
 
1. An electrolyte produced by gelation of a gelable system, wherein the gelable system comprises:
a lithium salt;
an ether compound comprising at least one cyclic ether compound and optionally a straight-chain ether compound; and
a polyester obtained by polycondensation of a polybasic acid or an acid anhydride with a polyhydric alcohol, wherein:
the polybasic acid is substituted or unsubstituted, selected from the group consisting oxalic acid, malonic acid, succinic acid, butenedioic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, sebacic acid, azelaic acid, and tricarballylic acid, and the substituents are one or more selected from the group consisting of alkyl, cycloalkyl, aryl, hydroxy, amino, ester, halogen, acyl, aldehyde, thiol, alkoxy, and mixtures thereof,
the acid anhydride is substituted or unsubstituted, selected from the group consisting of oxalic anhydride, malonic anhydride, succinic anhydride, maleic anhydride, glutaric anhydride, adipic anhydride, pimelic anhydride, sebacic anhydride, azelaic anhydride, hexahydrophthalic anhydride, and mixtures thereof, and
the substituents are independently selected from the group consisting of alkyl, cycloalkyl, aryl, hydroxy, amino, ester, halogen, acyl, aldehyde, thiol, alkoxy, and mixtures thereof;
wherein:
the electrolyte is a gel electrolyte, and, on a basis of mass fraction in the gelable system, the lithium salt is greater than or equal to 2 wt % and less than or equal to 20 wt %, and the at least one cyclic ether compound is more than or equal to 80 wt % and less than or equal to 98 wt %, and an optional gelable polymer and/or a gelable prepolymer is less than 1 wt % when present,
or
the electrolyte is a solid electrolyte, and, on the basis of mass fraction in the gelable system, the lithium salt is greater than or equal to 20 wt % and less than or equal to 50 wt %, the at least one cyclic ether compound is more than or equal to 50 wt % and less than or equal to 80 wt %, and the optional gelable polymer and/or gelable prepolymer is 1 wt % when present, and
the at least one cyclic ether compound is selected from the group consisting of

OG Complex Work Unit Chemistry

OG Complex Work Unit Chemistry

OG Complex Work Unit Chemistry

OG Complex Work Unit Chemistry

OG Complex Work Unit Chemistry

OG Complex Work Unit Chemistry

OG Complex Work Unit Chemistry