| CPC H01L 21/76837 (2013.01) [H01L 21/02112 (2013.01); H01L 21/0228 (2013.01); H01L 21/76877 (2013.01)] | 13 Claims | 

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               1. A method of filling a gap on a surface of a substrate, the method comprising the steps of: 
            providing a substrate within a first reaction chamber, the substrate comprising the gap; 
                forming a material layer on a surface of the substrate within the first reaction chamber; 
                exposing the material layer to a halogen reactant in a second reaction chamber to thereby form a flowable layer comprising a halogen within the gap; and 
                exposing the flowable layer to a converting reactant in a third reaction chamber to form a converted material within the gap. 
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