US 12,419,304 B2
Aryl sulfide comprising benzylamine, synthesis method and application thereof
Ning Li, Binzhou (CN); Yingshuai Liu, Binzhou (CN); Xianjiang Li, Binzhou (CN); Jian Xiao, Binzhou (CN); Xiangwei Liu, Binzhou (CN); Ruibin Liu, Binzhou (CN); Guozhu Sheng, Binzhou (CN); Ruijie Feng, Binzhou (CN); Xiaozhong Xiang, Binzhou (CN); Yingrui Cui, Binzhou (CN); Yu Chen, Binzhou (CN); and Shiling Wang, Binzhou (CN)
Assigned to SHANDONG KANGQIAO BIO-TECHNOLOGY CO., LTD., Binzhou (CN)
Filed by Shandong Kangqiao Bio-Technology Co., Ltd., Binzhou (CN)
Filed on Aug. 9, 2021, as Appl. No. 17/397,984.
Application 17/397,984 is a continuation in part of application No. PCT/CN2020/000198, filed on Aug. 31, 2020.
Claims priority of application No. 201910900234.4 (CN), filed on Sep. 23, 2019; and application No. 202010796915.3 (CN), filed on Aug. 10, 2020.
Prior Publication US 2021/0360919 A1, Nov. 25, 2021
This patent is subject to a terminal disclaimer.
Int. Cl. A01N 41/10 (2006.01); A01N 33/10 (2006.01); A01N 33/18 (2006.01); A01N 37/34 (2006.01); A01N 37/44 (2006.01); A01P 7/02 (2006.01); C07C 317/36 (2006.01); C07C 319/14 (2006.01); C07C 323/36 (2006.01)
CPC A01N 41/10 (2013.01) [A01N 33/10 (2013.01); A01N 33/18 (2013.01); A01N 37/34 (2013.01); A01N 37/44 (2013.01); A01P 7/02 (2021.08); C07C 317/36 (2013.01); C07C 319/14 (2013.01); C07C 323/36 (2013.01)] 3 Claims
 
1. An aryl sulfide of formula I, or an agriculturally acceptable salt thereof,

OG Complex Work Unit Chemistry
wherein:
n is 0 or 1;
X is fluorine, chlorine, or methyl;
Y is chlorine or methyl;
R1 is hydrogen, fluorine, chlorine, bromine, hydroxyl, nitro, hydroxymethyl, a cyano group, trifluoromethyl, C1-3 alkyl, C1-4 alkoxycarbonyl, acetyl, propionyl, C1-3 alkoxy, ethylthio, 2-fluoroethanothioxy, 2-chloroethanothioxy, 2,2-difluoroethylthio, 2,2,2-trifluoroethylthio, propylthio, 2,2,2-trifluoroethylsulfinyl, vinyloxycarbonyl, 2,2,2-trifluoroethoxycarbonyl, or n-methylcarbonyl;
R2 is hydrogen, fluorine, or chlorine;
R3 is hydrogen, fluorine, chlorine, bromine, or a cyano group;
R4 and R5 at each occurrence represent hydrogen; and
R6 is n-propyl or 2,2,2-trifluoroethyl.