US 12,095,079 B2
Elastic network polymer-encapsulated anode particles for lithium batteries and method of manufacturing
Hui He, Dayton, OH (US); and Bor Z. Jang, Centerville, OH (US)
Assigned to Honeycomb Battery Company, Dayton, OH (US)
Filed by Global Graphene Group, Inc., Dayton, OH (US)
Filed on Dec. 21, 2020, as Appl. No. 17/128,798.
Prior Publication US 2022/0199977 A1, Jun. 23, 2022
Int. Cl. H01M 4/36 (2006.01); H01M 4/62 (2006.01); H01M 10/0525 (2010.01); H01M 4/02 (2006.01)
CPC H01M 4/366 (2013.01) [H01M 4/622 (2013.01); H01M 4/625 (2013.01); H01M 10/0525 (2013.01); H01M 2004/021 (2013.01); H01M 2004/027 (2013.01)] 27 Claims
OG exemplary drawing
 
1. A composite particulate for a lithium battery, comprising one or more anode active material particles that are dispersed in a high-elasticity polymer matrix or encapsulated by a high-elasticity polymer shell, wherein said high-elasticity polymer matrix or shell has a recoverable elastic tensile strain no less than 5%, when measured without an additive or reinforcement dispersed therein, and a lithium ion conductivity no less than 10−8 S/cm at room temperature and wherein said high-elasticity polymer comprises a crosslinked polymer network of chains from carboxymethyl cellulose (CMC), a substituted version thereof, or a derivative thereof, and wherein said composite particulate has a diameter from 10 nm to 50 μm, wherein said high-elasticity polymer contains a cross-linked network of CMC crosslinked by a crosslinking agent to a degree of crosslinking that imparts an elastic tensile strain from 5% to 500%, wherein said crosslinking agent is selected from N,N-methylene bisacrylamide, 1,4-butanediol diglycidyl ether, tetrabutylammonium hydroxide, cinnamic acid, ferric chloride, aluminum sulfate octadecahydrate, diepoxy, dicarboxylic acid compound, poly(potassium 1-hydroxy acrylate) (PKHA), glycerol diglycidyl ether (GDE), ethylene glycol, polyethylene glycol, polyethylene glycol diglycidyl ether (PEGDE), citric acid, methacrylic acid, a derivative compound of ac a derivative compound of methacrylic acid, glycidyl functions, N,N′-Methylenebisacrylamide (MBAAm), Ethylene glycol dimethacrylate (EGDMAAm), isobomyl methacrylate, methyl methacrylate, isobomyl acrylate, ethyl methacrylate, isobutyl methacrylate, n-Butyl methacrylate, ethyl acrylate, 2-Ethyl hexyl acrylate, n-Butyl acrylate, a diisocyanate, an urethane chain, a chemical derivative thereof, or a combination thereof.