US 12,414,318 B2
Fabrication of field effect transistors with ferroelectric materials
Cheng-Ming Lin, Kaohsiung (TW); Sai-Hooi Yeong, Hsinchu County (TW); Chi On Chui, Hsinchu (TW); Ziwei Fang, Hsinchu (TW); and Huang-Lin Chao, Hillsboro, OR (US)
Assigned to TAIWAN SEMICONDUCTIR MANUFACTURING CO., LTD., Hsinchu (TW)
Filed by Taiwan Semiconductor Manufacturing Co., Ltd., Hsin-Chu (TW)
Filed on Jun. 4, 2021, as Appl. No. 17/339,615.
Application 17/339,615 is a division of application No. 16/454,854, filed on Jun. 27, 2019, granted, now 11,031,490.
Prior Publication US 2021/0296503 A1, Sep. 23, 2021
Int. Cl. H10D 30/01 (2025.01); H01L 21/02 (2006.01); H10D 64/01 (2025.01); H10D 64/68 (2025.01)
CPC H10D 30/0415 (2025.01) [H01L 21/0206 (2013.01); H01L 21/02181 (2013.01); H01L 21/02356 (2013.01); H10D 64/017 (2025.01); H10D 64/689 (2025.01)] 20 Claims
OG exemplary drawing
 
1. A semiconductor structure, comprising:
a semiconductor layer disposed over a substrate;
a shallow trench isolation (STI) structure disposed over the substrate and surrounding the semiconductor layer;
gate spacers disposed over the semiconductor layer;
an interfacial layer disposed on the semiconductor layer;
a hafnium-containing dielectric layer of a same and uniform material in its entirety, wherein a first portion of the hafnium-containing dielectric layer having a first thickness is disposed on the interfacial layer and a second portion of the hafnium-containing dielectric layer having a second thickness is disposed along sidewalls of the gate spacers and interfacing side surfaces of a metal gate electrode, and wherein the first thickness is greater than the second thickness;
the metal gate electrode disposed over the hafnium-containing dielectric layer and between the gate spacers; and
source/drain features formed over the semiconductor layer, the source/drain features directly contact side surfaces of the gate spacers, wherein a top surface of the STI structure is below a bottom surface of the source/drain features,
wherein bottom surfaces of the interfacial layer, the second portion of the hafnium-containing dielectric layer, and the gate spacers are substantially coplanar,
wherein the hafnium-containing dielectric layer includes a ferroelectric orthorhombic phase in both the first and second portions of the hafnium-containing dielectric layer, wherein electric dipoles within both the first and second portions of the hafnium-containing dielectric layer are oriented substantially in a same direction parallel to an electric field that is applied when forming the first and second portions of the hafnium-containing dielectric layer.