US 12,410,523 B1
Integrated low k recovery and ALD metal deposition process for advanced technology node
Shinjae Kwon, Santa Clara, CA (US); Xinyi Lu, Santa Clara, CA (US); Fredrick Kim, Santa Clara, CA (US); Bo Xie, San Jose, CA (US); Chi-I Lang, Cupertino, CA (US); Li-Qun Xia, Santa Clara, CA (US); and Han Wang, Palo Alto, CA (US)
Assigned to Applied Materials, Inc., Santa Clara, CA (US)
Filed by Applied Materials, Inc., Santa Clara, CA (US)
Filed on Jul. 16, 2024, as Appl. No. 18/774,617.
Claims priority of provisional application 63/571,672, filed on Mar. 29, 2024.
Int. Cl. C23C 16/48 (2006.01); C23C 16/02 (2006.01); C23C 16/34 (2006.01); C23C 16/455 (2006.01); H01L 21/02 (2006.01)
CPC C23C 16/482 (2013.01) [C23C 16/0227 (2013.01); C23C 16/34 (2013.01); C23C 16/45525 (2013.01); H01L 21/0206 (2013.01); H01L 21/02277 (2013.01)] 21 Claims
OG exemplary drawing
 
1. A method, comprising:
positioning a substrate within a processing chamber, the substrate comprising a first low-k film having a first water contact angle, the first low-k film disposed over an interconnect structure;
cleaning the substrate within the processing chamber to form a cleaned substrate, the cleaned substrate comprising a damaged low-k film having a second water contact angle and the damaged low-k film is a product of the first low-k film;
exposing the cleaned substrate to a recovery precursor to form a recovered substrate, the recovered substrate comprising a recovered low-k film and the recovered low-k film is a product of the damaged low-k film;
exposing the recovered substrate to a UV light source to form a treated substrate, the treated substrate comprising a treated low-k film having a third water contact angle and the treated low-k film is a product of the recovered low-k film, wherein each of the first low-k film and the treated low-k film independently comprise a k value and the k value of the first low-k film is less than the k value of the treated low-k film; and
depositing a liner layer over the treated substrate via atomic layer deposition (ALD).