US 12,077,624 B2
Method for producing hydrocarbon resins and hydrogenation products thereof
Jun Liu, Düsseldorf (DE); and Manuel Nau, Haltern am See (DE)
Assigned to Rain Carbon Germany GMBH, Castrop-Rauxel (DE)
Appl. No. 16/970,047
Filed by Rain Carbon Germany GmbH, Castrop-Rauxel (DE)
PCT Filed Feb. 14, 2019, PCT No. PCT/EP2019/053652
§ 371(c)(1), (2) Date Jan. 29, 2021,
PCT Pub. No. WO2019/158638, PCT Pub. Date Aug. 22, 2019.
Claims priority of application No. 18156758 (EP), filed on Feb. 14, 2018.
Prior Publication US 2021/0189038 A1, Jun. 24, 2021
Int. Cl. C08F 232/06 (2006.01); C08F 212/08 (2006.01); C09J 125/08 (2006.01); C09J 145/00 (2006.01); C08F 8/04 (2006.01)
CPC C08F 232/06 (2013.01) [C08F 212/08 (2013.01); C09J 125/08 (2013.01); C09J 145/00 (2013.01); C08F 8/04 (2013.01); C08F 2500/02 (2013.01); C08F 2500/22 (2013.01)] 17 Claims
 
1. A method for manufacturing a hydrocarbon resin comprising at least one cyclic diolefin monomer component and at least one ethylenically unsaturated aromatic monomer component comprising
(a) heating to a temperature of at least 180° C. at a heating rate of 0.5 to 10° C./second a mixture comprising at least one cyclic diolefin monomer component and at least one ethylenically unsaturated aromatic monomer component having 8-13 carbon atoms, and
(b) polymerizing the mixture to form a hydrocarbon resin having a molecular weight of less than 2,500 g/mol, the molecular weight characterized as the centrifuge average (z-average) molecular weight,
wherein the mixture comprises a single phase liquid during heating and polymerization.