| CPC H10B 12/053 (2023.02) [H01L 21/02233 (2013.01); H01L 21/76202 (2013.01); H10B 12/34 (2023.02)] | 14 Claims |

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1. A method of forming semiconductor structures, comprising:
forming an opening to create an isolation region in a semiconductor substrate;
performing a first portion of an atomic layer deposition (ALD) at a first oxidation rate into the isolation region;
performing a second portion of the ALD at a second oxidation rate into the isolation region to form a void-free isolation trench; and
forming a buffer area between the semiconductor substrate and the isolation region during performance of the first portion of the ALD.
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