| CPC H01L 21/76837 (2013.01) [C23C 16/45553 (2013.01); H01L 21/0228 (2013.01)] | 17 Claims |

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1. A method of filling a gap, the method comprising
providing a substrate to a reaction chamber, the substrate comprising the gap;
exposing the substrate to a precursor and to a reactant, at least one of the precursor and the reactant comprising a metal or a metalloid, and at least one of the precursor and the reactant comprising a halogen;
thereby allowing the precursor and the reactant to form a gap filling fluid; and,
thereby at least partially filling the gap with a gap filling fluid, the gap filling fluid comprising the metal or the metalloid, and
exposing the substrate to a transformation treatment
wherein the transformation treatment comprises exposing the substrate to ultraviolet radiation.
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