| CPC H01C 7/021 (2013.01) [H01C 1/1406 (2013.01)] | 14 Claims |

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1. An over-current protection device, comprising:
a first electrode layer;
a second electrode layer; and
a positive temperature coefficient (PTC) material layer laminated between the first electrode layer and the second electrode layer, the PTC material layer comprising:
a polymer matrix comprising a fluorine-free polyolefin-based polymer and a fluoropolymer, wherein the total volume of the PTC material layer is calculated as 100%, and the fluorine-free polyolefin-based polymer accounts for 41-55% and the fluoropolymer accounts for 5-7% by volume of the PTC material layer;
a conductive filler dispersed in the polymer matrix, thereby forming an electrically conductive path in the PTC material layer; and
a titanium-containing inner filler dispersed in the polymer matrix, wherein the titanium-containing inner filler has a compound represented by a general formula (I):
MTiO3 (I)
wherein the M represents transition metal or alkaline earth metal, and the total volume of the PTC material layer is calculated as 100%, and the titanium-containing inner filler accounts for 1-9% by volume of the PTC material layer.
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